Decorating UiO-66-NH2 crystals on recyclable fiber bearing polyamine and amidoxime bifunctional groups via cross-linking method with good stability for highly efficient capture of U(VI) from aqueous solution.

Although polyacrylonitrile fiber (PANF) and metal-organic frameworks (MOFs) have been extensively investigated to remove U(VI) from water, their practical applications are seriously hindered by the relatively low stability of PANF in acidic solution and great difficulty of separating MOFs nanoparticles from solution, beside that, little attention is paid to the fabrication of MOFs and PANF composite materials (MPCMs) with excellent adsorption capacity for U(VI). Herein, we report the synthesis of novel MPCMs by decorating different concentrations of UiO-66-NH2 crystals onto polyamine and amidoxime groups functionalized PANF (PA-AO-PANF) through cross-linking method for U(VI) extraction. The characterization results reveal that the combination of PA-AO-PANF and UiO-66-NH2 crystals endows MPCMs with excellent separation ability, large surface area, good stability and plentiful surface functional groups, which contributes to good selectivity and enhanced adsorption performance. Consequently, the obtained UN-PA-AO-PANF-2 shows the maximum uptake capacity of 441.8 mg/g and equilibrium uptake time of 30 min towards U(VI). Besides, the U(VI) uptake ability and structure of UN-PA-AO-PANF-2 are well preserved after ten adsorption-desorption cycles. With these outstanding properties, the adsorbent has great potential for the capture of U(VI) from aqueous solutions. Importantly, this work provides a cost-effective and efficient way to construct extremely stable MPCMs hybrid fibers.

All-Climate High-Voltage Commercial Lithium-Ion Batteries Based on Propylene Carbonate Electrolytes.

Propylene carbonate (PC)-based electrolytes have many attractive advantages over the commercially used ethylene carbonate (EC)-based electrolytes like a wider operating temperature and higher oxidation stability. Therefore, PC-based electrolytes become the potential candidate for lithium-ion batteries with higher energy density, longer lifespan, and better low- and high-temperature performance. In spite of the superiority, PC is incompatible with the graphite anode because PC fails to passivate the graphite anode, leading to severe decomposition and gas evolution, which seriously restrict the development of the PC-based electrolytes. Nevertheless, it is recently found that the usage of diethyl carbonate (DEC) as a cosolvent will greatly improve the anodic tolerance of PC to realize the reversible lithiation/delithiation of the graphite anode in the PC-based electrolyte. It is because DEC induces anions into the solvation shell of Li+ to form an anion-induced ion-solvent-coordinated (AI-ISC) structure with higher reduction stability. In this work, we fabricated 4.4 V pouch cells to assess in detail the practical viability of the PC-based electrolyte in a commercial battery system. In comparison to conventionally used EC-based cells, the pouch cells with the PC-based electrolyte exhibit more excellent high-voltage tolerance and electrochemical performance at all temperature ranges (-40 to 85 °C), demonstrating the wide application prospect of the PC-based electrolyte.